EPR parameters and impurity structures for Cr3+ ions in KSc(MoO4)2, RbIn(MoO4)2 and RbSc(MoO4)2 crystals.
Identifieur interne : 002E05 ( Main/Exploration ); précédent : 002E04; suivant : 002E06EPR parameters and impurity structures for Cr3+ ions in KSc(MoO4)2, RbIn(MoO4)2 and RbSc(MoO4)2 crystals.
Auteurs : RBID : pubmed:15741128English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Chromium, Indium, Molybdenum, Potassium Compounds, Rubidium.
- Crystallization, Electron Spin Resonance Spectroscopy, Mathematics.
Abstract
The calculations of EPR parameters (g factors g||, g(perpendicular) and zero-field splitting D) related to the impurity structures have been made from the high-order perturbation formulas for Cr(3+) ions in trigonal KSc(MoO(4))(2), RbIn(MoO(4))(2) and RbSc(MoO(4))(2) crystals. It is found that the MO(6) octahedra in these crystals change from the trigonal elongation in the pure crystals to the trigonal compression in the impurity centers. The results are discussed.
DOI: 10.1016/j.saa.2004.06.047
PubMed: 15741128
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China. zhangwc1@163.com</nlm:affiliation><country wicri:rule="url">Colombie</country></affiliation></author><author><name sortKey="Qing, Zhou" uniqKey="Qing Z">Zhou Qing</name></author><author><name sortKey="Xiao Xuan, Wu" uniqKey="Xiao Xuan W">Wu Xiao-Xuan</name></author><author><name sortKey="Yang, Mei" uniqKey="Yang M">Mei Yang</name></author></titleStmt><publicationStmt><date when="2005">2005</date><idno type="doi">10.1016/j.saa.2004.06.047</idno><idno type="RBID">pubmed:15741128</idno><idno type="pmid">15741128</idno><idno type="wicri:Area/Main/Corpus">002F79</idno><idno type="wicri:Area/Main/Curation">002F79</idno><idno type="wicri:Area/Main/Exploration">002E05</idno></publicationStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chromium (chemistry)</term><term>Crystallization</term><term>Electron Spin Resonance Spectroscopy</term><term>Indium (chemistry)</term><term>Mathematics</term><term>Molybdenum (chemistry)</term><term>Potassium Compounds (chemistry)</term><term>Rubidium (chemistry)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Chromium</term><term>Indium</term><term>Molybdenum</term><term>Potassium Compounds</term><term>Rubidium</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Crystallization</term><term>Electron Spin Resonance Spectroscopy</term><term>Mathematics</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The calculations of EPR parameters (g factors g||, g(perpendicular) and zero-field splitting D) related to the impurity structures have been made from the high-order perturbation formulas for Cr(3+) ions in trigonal KSc(MoO(4))(2), RbIn(MoO(4))(2) and RbSc(MoO(4))(2) crystals. It is found that the MO(6) octahedra in these crystals change from the trigonal elongation in the pure crystals to the trigonal compression in the impurity centers. The results are discussed.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">15741128</PMID><DateCreated><Year>2005</Year><Month>03</Month><Day>02</Day></DateCreated><DateCompleted><Year>2005</Year><Month>08</Month><Day>05</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print"><Journal><ISSN IssnType="Print">1386-1425</ISSN><JournalIssue CitedMedium="Print"><Volume>61</Volume><Issue>6</Issue><PubDate><Year>2005</Year><Month>Apr</Month></PubDate></JournalIssue><Title>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</Title><ISOAbbreviation>Spectrochim Acta A Mol Biomol Spectrosc</ISOAbbreviation></Journal><ArticleTitle>EPR parameters and impurity structures for Cr3+ ions in KSc(MoO4)2, RbIn(MoO4)2 and RbSc(MoO4)2 crystals.</ArticleTitle><Pagination><MedlinePgn>1243-6</MedlinePgn></Pagination><Abstract><AbstractText>The calculations of EPR parameters (g factors g||, g(perpendicular) and zero-field splitting D) related to the impurity structures have been made from the high-order perturbation formulas for Cr(3+) ions in trigonal KSc(MoO(4))(2), RbIn(MoO(4))(2) and RbSc(MoO(4))(2) crystals. It is found that the MO(6) octahedra in these crystals change from the trigonal elongation in the pure crystals to the trigonal compression in the impurity centers. 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